Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(ii)-polypyridine complexes with phenolate ions.
Keywords:
bpy = 2.2’-bipyridine, NN= polypyridy1 ligand,Abstract
Ruthenium (II)- polypyridy1 complexes of similar size but with variable reduction potential undergo efficient photoinduced electron- transfer reactions with phenolate ions in aqueous medium. All these reactions are exergonic and are in accordance with the Marcus theory of electron transfer. At high negative G° Marcus inverted region is observed in this bimolecular photoinduced charge separation reaction.
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Published
21-01-2012
How to Cite
Verma, S., P. N. Tripathi, and R. P. Singh. “Marcus Inverted Region in the Photoinduced Electron Transfer Reactions of ruthenium(ii)-Polypyridine Complexes With Phenolate Ions”. International Multidisciplinary Research Journal, vol. 2, no. 1, Jan. 2012, https://updatepublishing.com/journal/index.php/imrj/article/view/1542.
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Research Articles