Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(ii)-polypyridine complexes with phenolate ions.

Authors

  • Smriti Verma Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India
  • P N Tripathi Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India
  • Rajesh P Singh Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Keywords:

bpy = 2.2’-bipyridine, NN= polypyridy1 ligand,

Abstract

Ruthenium (II)- polypyridy1 complexes of similar size but with variable reduction potential undergo efficient photoinduced electron- transfer reactions with phenolate ions in aqueous medium. All these reactions are exergonic and are in accordance with the Marcus theory of electron transfer. At high negative G° Marcus inverted region is observed in this bimolecular photoinduced charge separation reaction.


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Author Biographies

Smriti Verma, Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

P N Tripathi, Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Rajesh P Singh, Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Department of Chemistry, Kisan Post-Graduate College, Bahraich 271801 (U.P.) India

Published

21-01-2012

How to Cite

Verma, S., P. N. Tripathi, and R. P. Singh. “Marcus Inverted Region in the Photoinduced Electron Transfer Reactions of ruthenium(ii)-Polypyridine Complexes With Phenolate Ions”. International Multidisciplinary Research Journal, vol. 2, no. 1, Jan. 2012, https://updatepublishing.com/journal/index.php/imrj/article/view/1542.

Issue

Section

Research Articles